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Q.

Statement I α D(+) Glucose and β  - D(+) Glucose are pair of diastereomers
Statement II : Rate of enzyme catalysed hydrolysis of sucrose is faster than rate of acid catalysed hydrolysis of sucrose 

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a

Both Statement-I and Statement-II are true.

b

Statement-I  is true but Statement-II is not  true

c

Statement-I  is not  true but Statement-II is  true

d

Both Statement-I and Statement-II are not true

answer is A.

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Detailed Solution

Both α D(+) Glucose and  β - D(+) Glucose are non super imposable non mirror images. Hence both are diastereomers. 

Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 KJ mol, while the activation energy is only 2.15 KJ mol when hydrolysis is catalysed by the enzyme sucrase.

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Statement I : α− D(+) Glucose and β  - D(+) Glucose are pair of diastereomersStatement II : Rate of enzyme catalysed hydrolysis of sucrose is faster than rate of acid catalysed hydrolysis of sucrose