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Q.

Statement-I: Dipole moment of NF3is less than that of NH3 

Statement-2: Polarity of N-F bond is less than that of N-H bond

Choose the correct option:

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a

Statement-I is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-I.

b

Statement-I is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-I.

c

Statement-I is True, Statement-2 is False.

d

Statement-I is False, Statement-2 is True.

answer is C.

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Detailed Solution

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Dipole moment vectors are in compensatory mode.

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Dipole moment vectors are additive in nature.

Each N-H bond in NH3 has a dipole moment that is directed toward nitrogen because H is less electronegative than nitrogen. The dipole moment of the resulting molecule, which has a tetrahedrally structured molecule with three N-H bonds, points in the same direction as the dipole produced by the nitrogen lone pair. However, because F is more electronegative than N in NF3, the outcome is different from that of a lone pair dipole. decreasing the net dipole as a result.

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