Q.

Statement-I: Fluoromethane CH3F;μ=1.85D has a smaller dipole moment than chlorometbane CH3Cl;μ=1.87D

Statement-2: Fluorine has less electron affinity than that of chlorine.

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a

Statement-1 is False, Statement-2 is True.

b

Statement-1 is True, Statement-2 is False

c

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

d

Statement-I is True, Statement-2 is True, Statement-2 
Is NOT a correct explanation for Statement-1.

answer is B.

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Detailed Solution

The dipole moment of Fluoromethane is 1.85 which is less than that of chlorometbane (1.87 D).

Fluorine has a lower electron affinity than chlorine. This is because of the factors listed below: In contrast to chlorine, which has seven electrons in its 3p-subshell, fluorine has seven electrons in its 2p-subshell. Comparatively, 3p-subshell is larger than 2p-subshell.

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Statement-I: Fluoromethane CH3F;μ=1.85D has a smaller dipole moment than chlorometbane CH3Cl;μ=1.87DStatement-2: Fluorine has less electron affinity than that of chlorine.