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Q.

Statement I: HF is thermally most stable hydrogen halide.
Statement II:  O2F2 is used in the removal of plutonium as PuF6 from spent nuclear fuel.

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a

Both statement I and statement II are false

b

Both statement I and statement II are true

c

Statement I is false and statement II is true

d

Statement I is true and statement II is false

answer is A.

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Detailed Solution

(1)The thermal stability of these halides decreases down the group, due to decrease in bond (H-X) dissociation enthalpy.

Thus, HF> HCl > HBr > HI

(2)Pu+3O2​F2PuF6​+3O2 ; unreacted Pu is separated by fluorination.

Both statements are correct

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Statement I: HF is thermally most stable hydrogen halide.Statement II:  O2F2 is used in the removal of plutonium as PuF6 from spent nuclear fuel.