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Q.

Statement I: Ideal solutions follow Raoult’s law.
Statement II:  ΔH and ΔV of ideal solutions are zero

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is A.

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Detailed Solution

For an Ideal sol.

Magnitude of A-B interactions = magnitude of A-A & B-B interaction

Neither attractions nor repulsions dominate

If A & B are two pure volatile liquids

\large P_A=P_A^oX_A \;\;;\;\;P_B=P_B^oX_B

No new attractions (or) repulsions in the mix.

No heat is liberated (or) absorbed (\large \Delta H_{mix.}=0)

No vol. changes (\large \Delta V_{mix.}=0)

I & II are correct

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Statement I: Ideal solutions follow Raoult’s law. Statement II:  ΔH and ΔV of ideal solutions are zero