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Q.

Statement I:  If a volume is kept constant and an inert gas such as argon is added which does not take part in the reaction, the equilibrium remains undisturbed.
Statement II:  It is because the addition of an inert gas at constant volume does not change the partial pressure or the molar concentrations of the substance involved in the reaction.

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a

Statement I is correct and statement II is incorrect.

b

Statement I is incorrect and statement II is correct.

c

Both statements I and II are incorrect.

d

Both statements I and II are correct.

answer is A.

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Detailed Solution

If the volume is kept constant and an inert gas such as argon is added which does not take part in the reaction, the equilibrium remains undisturbed. It is because the addition of an inert gas at constant volume does not change the partial pressures or the molar concentrations of the substance involved in the reaction. The reaction quotient changes only if the added gas is reactant or product involved in the reaction.

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