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Statement-I : is ${[T i {(H_{2} O)}_{6}]}^{3 +}$ colourless while ${[S c {(H_{2} O)}_{6}]}^{3 +}$ is coloured.
Statement-II : d-d transition are possible in ${[S c {(H_{2} O)}_{6}]}^{3 +}$ .
In the light of the above statements, choose the most appropriate answer from the options given below

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Both Statement I and Statement II are true

Statement I is false but Statement II is true

Statement I is true but Statement II is false

Both Statement I and Statement II are false

answer is D.

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Detailed Solution

${[S c {(H_{2} O)}_{6}]}^{3 +}$ has no unpaired electron in its d-subshell and thus d-d- transition is not possible ${[T i {(H_{2} O)}_{6}]}^{3 +}$ has one unpaired electron in its d-subshell which gives rise to d-d transition.

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