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Q.

Statement-I: Oxidizing power of VO2+<Cr2O72<MnO4
Statement-II: Stability of V+3<Cr+3< Mn+2 formed by the reductions of VO2+,Cr2O72andMnO4

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a

statement-I is true and statement-II is false

b

Statement-I is false but statement-II is true

c

Both statements are false

d

Both statements are true

answer is A.

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Detailed Solution

Oxidizing power order:  VO2+<Cr2O7-2<MnO4-  

Stability order:               VO2+>Cr2O7-2>MnO4-

In transition elements while moving from left to right lower oxidation state stability increases. Hence, their oxidizing ability increases and easily converted into lower oxidation states.

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Statement-I: Oxidizing power of VO2+<Cr2O7−2<MnO4−Statement-II: Stability of V+3<Cr+3< Mn+2 formed by the reductions of VO2+,Cr2O7−2 and MnO4−