Q.

Statement-I : PH3CC6H4NO2 is more reactive than PO2NC6H4NO2 towards electrophile.
Statement-II :-CH3 is ortho/para directing group while -NO2 is meta directing group. In the light of the above statements, choose the most appropriate answer from the options given below.

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a

Statement-I is incorrect but Statement-II is correct

b

Both Statement-I and Statement-II are correct

c

Statement-I is correct but Statement-II is incorrect

d

Both Statement-I and II are incorrect

answer is C.

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Detailed Solution

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nitro group shows negative mesomeric effect and negative inductive effect.

methyl group can show positive inductive effect and hyperconjugation

 

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