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Q.

Statement I: Solubility of NaCl is more in D2O than in water
Statement II : Molecular weight of D2O is more than that of water

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is C.

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Detailed Solution

→Dielectric constant is a measure of ionisation of ionic bond.
The solubility of NaCl in water & D2O depends upon the dielectric constant of H2O ,D2O 

Dielectric Constant(D) : D2O < H2O  

 As the dielectric constant of solvent ↑es,Solubility increase
→ Therefore, NaCl is more soluble in H2O than in D2O
Since 

DD2O<DH2O

 

Statement -I Wrong
→Molecular weight: D2O > H2O
  Statement -II correct

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