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Q.

Statement I  

van der Waals radius of an element is always larger than its covalent radius

Statement II 

Two molecules can never be closer than two atoms in a molecule 

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a

Statement I is incorrect and statement II is correct 

b

Statement I is correct and statement II is incorrect 

c

Both statements I and II are incorrect 

d

Both statements I and II are correct  

answer is D.

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Detailed Solution

van der Waals forces are weaker than a chemical bond, hence two 

molecules can never be closer than two atoms in a molecule. Thus van der Waals radius of an element is always greater than its covalent radius.

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