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Q.

Statement I: When a solution of non-volatile solute in water is cooled slightly below its freezing temperature, some ice separates out and then freezing stops.
Statement II: Separation of ice increases the molality of the left over solution.

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is A.

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Detailed Solution

When a solution of non-volatile solute in water is cooled slightly below its freezing temperature,

Ice separates out and then freezing stops ..... true

Below FP of any liquid, freezing is always a spontaneous process and the excess solvent separates out as a solid

(I) is true

The left over solution contains relatively lesser solvent , its concentration (molality) increases

(II) is true

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Statement I: When a solution of non-volatile solute in water is cooled slightly below its freezing temperature, some ice separates out and then freezing stops. Statement II: Separation of ice increases the molality of the left over solution.