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Q.

Statement-I: Xe-atom in XeF2 assumes sp-hybrid state.

Statement-2: XeF2 molecule does not follow octet rule.

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a

Statement-I is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-I.

b

Statement-I is True, Statement-2 is True, Statement-2 
Is NOT a correct explanation for Statement-I. 

c

Statement-I is False, Statement-2 is True

d

Statement-I is True, Statement-2 is False

answer is D.

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Detailed Solution

The Xe molecule is in an excited state in XeF2. The Xenon's electron configuration shifts to s2p5, and d1, with two unpaired electrons. As a result, the core atom, Xe, hybridises in an sp3d manner. As a result, the XeF2 molecule hybridization is sp3d.
The octet rule is broken by Xe. In fact, it bonds. It has a capacity of more than 8 electrons. Xenon can accommodate more than 8 electrons because it has valence electrons in the fourth energy level and access to the fourth sublevel.

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