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Statement-I: ${PCl}_{5}$ is covalent in gaseous and liquid state but ionic in solid state.
Statement-2: The solid state of ${PCl}_{5}$ consists of tetrahedral cation and octahedral anion.
Choose the correct option:

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Statement-I is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-I.

Statement-I is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-I.

Statement-I is True, Statement-2 is False.

Statement-I is False, Statement-2 is True.

answer is B.

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Detailed Solution

The reaction is,

${PCl}_{5} (s) ⟶ {PCl}_{4}^{+} + {PCl}_{6}^{-}$

In its solid state, ${PCl}_{5}$ is composed of the octahedral ${PCl}_{6}$ anion and the tetrahedral ${PCl}_{4 +}$ cation. In its liquid and gaseous states, ${PCl}_{5}$ is a trigonal bipyramidal structure featuring an ${sp}_{3} d$ hybridized P atom.

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