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Q.

Statement-I: PF5 keeps trigonal bipyramidal structure in gas as well as in solid state.

Statemeot-2:  PCl5 in gas and liquid state is covalent but in solid state it is ionic and exist as

PCl4+ and PCl6

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a

Statement-I is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-I.

b

Statement-I is True, Statement-2 is True, Statement-2 
Is NOT a correct explanation for Statement-I. 

c

Statement-I is False, Statement-2 is True

d

Statement-I is True, Statement-2 is False

answer is B.

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Detailed Solution

PF5 keeps trigonal bipyramidal structure in gas as well as in solid state Because, PF5 is trigonal bipyramidal and contains an sp3d hybridised P atom in the liquid and gaseous states; in the solid state, it is composed of the cations tetrahedral PCl4  and anion octahedral PCl6.

In its solid state, PCl5 is composed of the octahedral PCl6- anion and the tetrahedral PCl4+ cation. In its liquid and gaseous states, PCl5 is a trigonal bipyramidal structure featuring an sp3d hybridised P atom. Read more at Sarthaks.com: assertion-pcl5-is-covalent-in-gaseous-and-liquid-states-but-ionic-in-solid-state.

 

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