Q.

Statement(I):  S-orbital electron will be more tightly bound to the nucleus than p-orbital electron.
Statement(II):  Zeff experienced by the electron decreases with increase of azimuthal quantum number (l).

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a

Statement(I) is incorrect and statement(II) is correct.

b

Statement(I) is correct and Statement(II) is incorrect.

c

Both statements(I) and (II) are incorrect.

d

Both Statements(I) and (II) are correct.

answer is A.

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Detailed Solution

  S-orbital electron will be more tightly bound to the nucleus than p-orbital electron due to the spherical shape of s-orbital it is nearest to nucleus.

 Zeff experienced by the electron decreases with increase of azimuthal quantum number (l).

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