Q.

Structure of FXeN (SO2F)2 (pale yellow solid) and FXeOSO2F are given below :

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Select the correct statements. (It is observed that geometry of nitrogen is planar with respect to its surrounding atom)

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a

9d-orbitals are involved in bonding in structure (I)

b

Maximum seven atoms may lie in one plane in structure (I)

c

10 atoms are sp3 hybridized in structure (I)

d

S-O bond length of (II) is smaller than S-N bond length in (I)

answer is A, D.

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Detailed Solution

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Xesp3d

Ssp3 (No. ofpπdπ: bonds = 4)

Nsp2

(d)  S-O bond length in (II) is smaller because of resonance.

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