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Q.

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law,
with t1/2 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours?

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a

1.158 M

b

0.518 M

c

0.158 M

d

3.182 M

answer is C.

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Detailed Solution

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t12=0.693k k=0.693t12 k=0.6933=0.231

Let initial concentration of sucrose be 1 M.
After 8 hours, the concentration will be 1−x. 

x represents the amount of sucrose decomposed.
k=2.303tlog[A]o[A]


0.231= 2.3038 log11x   log11x=0.8024   11x=6.345 x=0.842

After 8 hours, the concentration of sucrose left = 1−0.842=0.158 M.

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