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Q.

Sulphide ion in alkaline solution reacts with solid sulphur to form polysulpbide ions having formulae S22,S32,S42 and so on. The equilibrium constant for the formation of S22 is 12K1 and for the formation of S32 is 132K2, both from S and S2 What is the equilibrium constant for the formation of S32 from S22 and S?

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a

11

b

132

c

12

d

None of these

answer is A.

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Detailed Solution

Here, the reactions are;

S+S2S22   ......(i)

2S+S2S32  ......(ii)

S22+SS32  .......(iii)

So,

K=K2K1 K=13212=11

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