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Q.

Sulphurous acid (H2SO3) has Ka1 = 1.7 x 10-2 and Ka2 = 6.4 x 10-8. The pH of 0.588M H2SO3
is ____. (Round off to the Nearest Integer).

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answer is 1.

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Detailed Solution

H2SO3 is dibasic acid, But according to data Ka2<<<Ka1 So pH is only due to Ka1
H2S3(aq)H+(aq)+HSO3(aq)Ka1=1.7×102
t = 0   C   0   0
t=t  Dissociated Produced 
           Cα         Cα         Cα 
t = teq Left    Present
         C- Cα       Cα               Cα 
        C(1-α)        Cα              Cα
ka1=C2α2C(1α) as α<<1 so 1α is ignored
Ka1=2 α=Ka1CH3O+==C×Ka1C=Ka1C=1.7×102×0.58812=0.999×10212=1×10212pH=logH3O+=log10212=12×(1)×(2log10)=1

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