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Q.

Sum of the spin only magnetic moment (in the units of B.M.) of the following complexes:

[Cu(NH3)4]2+;[Fe(CN)6]3;[NiCl4]2;[CoF6]3;[Fe(H2O)5(NO)]SO4 [Given:2=1.41,3=1.73,5=2.24,7=2.64,15=3.87,24=4.90]

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answer is 15.05.

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Detailed Solution

Complex                                   Magnetic moment

[Cu(NH3)4]2+                       3=1.73  B.M

[Fe(CN)6]3                         3=1.73  B.M

[NiCl4]2                              22=2.82B.M

[CoF6]3                              24=4.90B.M

[Fe(H2O)5(NO)]SO4        15=3.87B.M

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Sum of the spin only magnetic moment (in the units of B.M.) of the following complexes:[Cu(NH3)4]2+;[Fe(CN)6]3−;[NiCl4]2−;[CoF6]3−;[Fe(H2O)5(NO)]SO4 [Given: 2=1.41,3=1.73,5=2.24,7=2.64,15=3.87,24=4.90]