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Q.

Suppose the elements X and Y combine to form two compounds XY2 and X3Y2 When 0.1 mole of XY2  weighs 10 g and 0.05 mole of X3Y2 weighs 9 g, the atomic weights of X and Y are

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a

60,40

b

40,30

c

20,30

d

30,20

answer is A.

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Detailed Solution

Let atomic weight of element  X is x and that of element Y is y.
For XY2,n=wMol.wt.
0.1=10x+2yx+2y=100.1=100...............(i)
For X3Y2,n=wMol.wt.
0.5=93x+2y3x+2y=90.05=180...............(ii)
On solving equations (i) and (ii), we get 
x = 40
40+2y=1002y=60y=30
 

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