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Q.

Syrupy phosphoric acid contains 85% acid (wt./wt) and has a specific gravity of 1.69 gm cm-3 at 298 K. Assuming that the acid is completely dissociated  upto first dissociation stage, the molal concentration of H+ ions in the solution is

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a

38.6

b

57.8

c

19.3

d

29.0

answer is D.

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Detailed Solution

H3PO4H++H2PO4
Moles of acid  =1000×8598×15=57.8 moles kg1 Mol.wt.of H3PO4=98
Since the acid is dissociated up to 1st stage, molal conc. of
H+=57.83=19.3 molal

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