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Q.

(T) Imparts violet colour in the flame test

compd(U)+concH2SO4 (V)Red gas  NaOH+AgNO3

                                              (W)Red ppt NH3 soln. (X)

(W)Red ppt  dit. HCl (Y)White ppt

(U) Sublimes on heating NaOHΔ(Z)gan  

Identify (T) to (Z).

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a

T=KMnO4,U=HCl,V=Cl2,W=HgI2X=HgNH2NO3,Y=Hg2Cl2,Z=N2

b

T=K2Cr2O7,U=NH4Cl,V=CrO2Cl2W=Ag2CrO4,X=AgNH32+,Y=AgClZ=NH3

c

T=K2CrO4,U=KCl,V=CrO2Cl2,W=HgI2X=Na2CrO4,Y=BaCO3,Z=NH4Cl

d

T=K2MnO4,U=NaCl,V=CrO3,W=AgNO2X=NH42CrO4,Y=CaCO3,Z=SO2

answer is B.

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Detailed Solution

The reactions are,

Cr2O72(T)+6H++4NH4Cl2CrO2Cl2+4NH4+3H2O

CrO2Cl2+2NaOHNa2CrO4+2HCl

Na2CrO4+2AgNO3AgCrO4+2NaNO3                                                (W)

Ag2CrO4+4NH32AgNH32++CrO42    (W)                              (X)

Ag2CrO4+2HCl2AgCl+2H++CrO42                                      (Y)

NH4Cl+NaOHNH3+NaCl+H2O    (U)                          (Z)

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(T) Imparts violet colour in the flame test→compd⁡(U)+conc⋅H2SO4 (V)Red gas  →NaOH+AgNO3                                              (W)Red ppt →NH3 soln. (X)(W)Red ppt → dit. HCl (Y)White ppt(U) Sublimes on heating ⟶NaOHΔ(Z)gan  Identify (T) to (Z).