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Q.

Taking into account the motion of the nucleus of a hydrogen atom, choose the correct statements. Take  μ=M  meme+M;M: Mass of proton,  h=h/2π;h : planks constant

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a

Binding energy of electron in ground state is  μe432π202h2

b

Radius of nth orbit is  4π0n2h2μe2

c

Binding energy if motion of nuclei is not taken into account is more than the binding energy if nucleus motion is considered

d

If  meM=0.00055, percentage by which B.E. (Nucleus motion taken into account) differs from B.E. (Nucleus at rest) is 0.055%.

answer is A, B, C, D.

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Detailed Solution

Given that  M is the mass of the nucleus (proton) and m  the mass of electron. Proton and electron both revolve about their centre of mass (COM) with same angular velocity (ω)   but different linear speeds. Let  r1 and r2  be the distance of COM from proton and electron.
Let r  be the distance between the proton and the electron. Then
Mr1=mr2        r1+r2=r

      r1=mrM+m  and  r2=MrM+m

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Centripetal force to electron is provided by the electrostatic force.
 μr3ω2=e24πε0                        ...(1)
Moment of inertia of the atom about COM is :
 I=Mr12+mr22
or  I=(MmM+m)r2=μr2          ...(2)
According to Bohr’s theory  Iω=nh where  (h=h2π)
or  μr2ω=nh                         ...(3)
Solving equation (1) and (3) for  r we get
 r=4πε0n2h2μe2                         ...(4)
Electrical potential energy of the system is  U=e24πε0r
and kinetic energy is K=12Iω2=12μr2ω2 
But from equation (1)
ω2=e24πε0μr2                         K=e28πε0r

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