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Q.

Tendency for \large M_{(s)} \rightarrow M^{+3}_{(aq)} + 3e^- is highest for

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a

Ga

b

In

c

Al

d

Tl

answer is C.

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Detailed Solution

{M_{\left( S \right)}} \to {M^{ + 3}}_{\left( {aq} \right)} + 3{e^ - } 

For 13Th group elements the highest oxidation state is due to the involvement of valency ns electrons and np electrons

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The higher oxidation state stability from top to bottom in a group decreases.

Stability of +III oxidation state : Al+3 > Ga+3 > In+3 > Tl+3

\therefore Al is more stable in +3 oxidation state

Where as +1 oxidation state stability from top to bottom increases,due to inert pair effect.

Stability of +1 oxidation state : Ga+1 < In+1 < Tl+1

 

 

      

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Tendency for  is highest for