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Q.

 Test End Result
i)AlCl3(aq)+ Blue litmusp)Colloidal solution
ii)AlCl3(aq)+ Blue litmus +NH4OHdropbydropq)Red Coloration
iii)FeCl3+K4[Fe(CN)6]  (Excess)r)Blue floating mass
iv)Fe3+  +  SCNs)Blue Coloration
  t)Colourless solution

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a

i - q; ii  - t; iii – p,q; iv – q

b

i - q; ii - r, t; iii – p, s; iv – q

c

i – s; ii- q,r; iii – p,q; iv- p,t

d

i – s; ii-r, s; iii – p,s; iv – p,q

answer is B.

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Detailed Solution

When blue litmus is added to the solution of AlCl3, a red coloration is obtained due to the acidic nature of the solution. On addition of NH4OH solution drop by drop the solution becomes alkaline and aluminium hydroxide is precipitated.  Al(OH)3 adsorbs blue colour from the solution and forms insoluble adsorption complex named ‘lake’.  Thus, a blue mass floating in the colourless solution is obtained.  The test is therefore called lake test.
 FeCl3+K4[Fe(CN)6]KFe[Fe(CN)6] +3KCl 
                        (Excess)            (soluble Prussian blue)
                                                   (a colloidal solution)
Fe3++SCN[Fe(SCN)]2+  Blood red colour

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