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Q.

The ' f ' orbitals are half and completely filled, respectively in lanthanide ions
(Given: Atomic no. Eu, 63; Sm, 62; Tm, 69; Tb, 65; Yb,70;Dy,66) 

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a

Dy3+ and Yb3+

b

Tb4+ and Yb2+

c

Sm2+ and Tm3+

d

Eu2+ and Tm2+

answer is C.

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Detailed Solution


Tb4f96 s2 ;  Tb+44f7 

Yb4f146 s2 ; Yb+24f14

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The ' f ' orbitals are half and completely filled, respectively in lanthanide ions(Given: Atomic no. Eu, 63; Sm, 62; Tm, 69; Tb, 65; Yb,70;Dy,66)