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Q.

The formula dichlorobis (urea) copper (II) is

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a

$[Cu {[O = C {({NH}_{2})}_{2}]}_{2}] {Cl}_{2}$

b

$[{CuCl}_{2} {(O = C {({NH}_{2})}_{2})}_{2}]$

c

$[Cu [O = C {({NH}_{2})}_{2}] Cl] Cl$

d

$[{CuCl}_{2} [O = C {({NH}_{2})}_{2}] H_{2}]$

answer is B.

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Detailed Solution

In the given name of the complex, dicloro means that there are two Cl and bis (urea) indicates that there are two urea ligands (O=C(NH₂)₂)₂. Copper in the given complex has +2 oxidation state because each Cl has -1 charge whereas urea is a neutral ligand.

Formula of the complex is $[{CuCl}_{2} (O = C {{({NH}_{2})}_{2})}_{2}] .$

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