Q.

The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at25°C 3.0×104s4,104.4 KJ mol1 and 6.0×1014s1 respectively. The value of the rate constant asTmaximum  is

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a

6.0×1014s1

b

3.6×1030s1

c

2.0×108s1

d

Infinity

answer is B.

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Detailed Solution

Arrhenius Equation , k=AeEa/RT

If T  , then

 k = A.eEa/R

k=A;sinceEaR=0e0=1

Therefore, the value rate constant is equal to Arrhenius factor.

Hence, the rate constant k=6.0×1014s1 .

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