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Q.

The rate of a reaction triples when temperature changes from  20°C  to 50°C . Energy of activation for the reaction is (R=8.314JK1mol1)

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a

30 KJ mol1

b

28.81 KJ mol1

c

40 KJ mol1

d

25.81 KJ mol1

answer is B.

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Detailed Solution

The Arrhenius equitation is

logk2k1=EaR×2.303[T2T1T1T2]

Given that k2k1=3and R = 8.314 JK1mol1

T1=20+273=293K

T2=50+273=323K

log 3 = Ea8.314×2.303[323293323×293]

 Ea2.303×8.314×323×293×0.47730

           =28811.8 J mol1

 Ea=28.81KJ mol1

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