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Q.

The ratio of coefficients of HNO3,Fe(NO3)2  and NH4NO3  in the  redox equation Fe+HNO3Fe(NO3)2+NH4NO3+H2O in the balanced from will be

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a

10 : 1 : 4

b

10 : 4 : 1

c

4 : 10 : 1

d

4 : 1 : 10

answer is B.

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Detailed Solution

Fe0+HNO3+5Fe+2(NO3)2+NH43NO2+H2O

(i)Fe0Fe+2(NO3)22

(ii)HNO3+5NH43NO38

To make increase in O.N.=decrease, multiply eqn.

(i) by 4 and add. Hence

4Fe+HNO34Fe(NO3)2+NH4NO3

To balance N atoms on the two sides, multiply HNO3  by 10. Hence

4Fe+10HNO34Fe(NO3)2+NH4NO3

To balance O-atoms, add 3H2O  on RHS. Hence

4Fe+10HNO3

                          4Fe(NO3)2+NH4NO3+3H2O

H atoms are automatically balanced.

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