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Q.

The reaction for tarnish formation due to contact with hydrogen sulphide.

2Ag(s)+H2S(g)Ag2S(s)+H2(g)  and the above tarnish can be removed by using Al metal as

2Al+3Ag2SAl2S3+6Ag

The above two reactions appears to be a displacement reactions. But ‘Ag’ is less reactive than ‘H’ in reactivity series. Then what might be the reason.

i) ‘Ag’ can displace ‘H’ under certain conditions even though it is less reactive

ii) Ag cannot react directly with H2S  to displace ‘H’ from it.

iii) ‘Ag’ first oxidised to its oxide and then it reacts with H2S  to form Ag2S

iv) The formation of Ag2S  is possible by a decomposition reaction.

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a

i, ii, iii only

b

ii, iii only

c

ii, iii, iv only

d

All

answer is B.

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Detailed Solution

Ag cannot directly react with H2S  

ii) Ag cannot react directly with H2S  to displace ‘H’ from it.

iii) ‘Ag’ first oxidised to its oxide and then it reacts with H2S  to form Ag2S

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