Q.

The 1st , 2nd and the 3rd ionization enthalpies I1, I2 and I3, of four atoms with atomic numbers n, n+1, 
n+2 and n+3 , where n < 10, are tabulated below. Find correct statement(s)

Atomic numberIonization Enthalpy (kJ/mol) 
I1I2I3
n1681 33746050
n + 1208139526122
n + 249645626910
n + 373814517733

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a

Atomic number n+3 is highly electropositive

b

For the atomic number n+1, we can say that it has stable electronic configuration.

c

The value of n is 9.

d

The element with atomic number n belongs to p-Block

answer is A, B, C, D.

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Detailed Solution

Atomic numberIonization Enthalpy (kJ/mol) 
I1I2I3
n1681 33746050
n + 1208139526122
n + 249645626910
n + 373814517733

By observing the values of I1, I2 & I3 for atomic number (n+2), it is observed that I2 >>I1. 
This indicates that number of valence shell electrons is 1 and atomic number (n+2) should be an 
alkali metal.
Also for atomic number (n+3), I3 >> I2.
This indicates that it will be an alkaline earth metal which suggests that atomic number (n+1) 
should be a noble gas & atomic number (n) should belong to Halogen family. Since n < 10; hence 
n = 9 (F atom)
Note : n = 1 (H atom) cannot be the answer because it does not have I2 & I3 values. 

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