Q.

The acid dissociation constant (Ka)  for HCOOH,  ,  CH3COOH ,CH2ClCOOH and HCN at  25°C are  1.8×1041.8×105 ,  1.4×103 and 4.8×1010, respectively. The acid that gives highest pH at the equivalence point when 0.2 M solution of each acid is titrated with a 0.2 M solution of sodium hydroxide is:

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a

CH3COOH

b

HCOOH

c

CH2ClCOOH

d

HCN

answer is D.

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Detailed Solution

A+H2O HA+OH      Kh=KwKa

Less Ka more Kh, more pH.

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