Q.

The acid dissociation constants of H2S  and  HS are  107 and 1013  respectively. The pH of 0.1M  H2S aqueous solution will be _______

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answer is 4.

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Detailed Solution

As  Ka2<<Ka1,  H+ are mainly obtained from the first dissociation , second dissociation constant is extremely low when compare to first, therefore we can neglect Ka2 for calculation
 H2SH++HS for which 
[H+]=KC=107×101=104 pH=4

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