Q.

The active ingredient in commercial bleach is sodium hypochlorite, NaOCI, which can be determined by iodometric analysis as indicated in these equations.

OCl+2H++2II2+Cl+H2O I2+2S2O32S4O62+2I

If 1.356 gof a bleach sample requires 19.50 mL of  0.100 M Na2S2O3= solution, what is the percentage by mass of  NaOCl  in the bleach ?

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a

10.7%

b

3.70%

c

5.35%

d

2.68%

answer is C.

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Detailed Solution

Percentage by mass,

19.5×0.11000×12×[74.5]1.356×100


 

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