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Q.

The addition ofNH4CNS to a neutral solution of cobalt(II) salt produces

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a

red precipitates

b

green precipitates

c

yellow procipitates

d

blue precipitates

answer is C.

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Detailed Solution

The addition of  NH4CNS to a neutral solution of cobalt(II) salt produces blue precipitates.

The production of a complex ion, tetraisothiocyanatocobaltate(II) ion, when a concentrated solution of ammonium thiocyanate is added to solutions containing cobalt(II) ion gives rise to a blue color.

Acetone makes this complex ion more stable, and adding roughly the same amount of acetone will intensify the color blue precipitates.

Hence, option C is correct.

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