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Q.

The aerial oxidation of chloroform in sunlight to phosgene can be checked by

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a

Keeping chloroform in amber coloured bottles but not completely filled

b

Adding a few drops of 1%  C2H5OH

c

Adding a few drops of dil HCl  or  NaOH 

d

Both (a) and (b)

answer is D.

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Detailed Solution

Amber colored bottles- light absorption minimum 1 % C2H5OH  converts poisonous phosgene to non poisonous diethyl carbonate. Which is a solid and can be seen at the bottle of the container.

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The aerial oxidation of chloroform in sunlight to phosgene can be checked by