The alcohol, which easily reacts with conc. $HCl$ is

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${({CH}_{3})}_{3} - C - OH$

${({CH}_{3})}_{3} - CH - {CH}_{2} OH$

${CH}_{3} - {CH}_{2} - {CH}_{2} - {CH}_{2} - OH$

${CH}_{3} - CHOH - {CH}_{2} - {CH}_{3}$

answer is B.

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Detailed Solution

Tertiary alcohol readily reacts with halogen acid.

The presence of 3 alkyl groups increases electron density on 3°carbon atom. Hence -OH group is easily removed. After the removal of -OH group, 3° carbonium ion is formed, which is most stable.

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