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Q.

The alkaline CuSO4, containing sodium potassium tartrate does not react with

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a

CH3CHO

b

C2H5CHO

c

C6H5CH2CHO

d

C6H5CHO

answer is D.

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Detailed Solution

  • The alkaline CuSO4​, containing sodium potassium tartrate is Fehling solution and in aromatic aldehydes, the CHO group is attached to a benzene ring. 
  • Due to resonance, carbonyl group's C acquires a double bond character with the benzene, which is very strong to break. 
  • Oxidizing agents like Cu2+ are unable to break that bond, so such aldehydes are unable to show fehling's test.
  • Thus, C6​H5​CHO does not react with the alkaline CuSO4​, containing sodium potassium tartrate.
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