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Q.

The alkyne which gives aldehyde on acidic hydration in presence of ${Hg}^{2 +}$ at 333K is

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a

Propyne

b

But – 2 – yne

c

But –1-yne

d

Ethyne

answer is B.

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Detailed Solution

$CH \equiv CH + H_{2} O \to_{{HgSO}_{4} {,60}^{0} C}^{{30.%H}_{2} {SO}_{4}} (C H_{2} = {CHOH}^{}) ⇌ {CH}_{3} - CHO$

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The alkyne which gives aldehyde on acidic hydration in presence of Hg2+ at 333K is