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Q.

The amine, which can react with C6H5-SO2-Cl to form a product, insoluble in alkali shall be 

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a

Both primary and secondary amines

b

Primary amine 

c

Tertiary amine 

d

Secondary amine

answer is B.

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Detailed Solution

  • C6H5SO2CI is called Hinsberg's reagent. 
  • They react with secondary amine to form a product insoluble in alkali. 
  • This reaction used to separate 1°, 2° and 3° amine from their mixture. 
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The amine, which can react with C6H5-SO2-Cl to form a product, insoluble in alkali shall be