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Q.

The ammonia (NH3) released on quantitative reaction of 0.6 g urea (NH2CONH2) with sodium hydroxide (NaOH) can be neutralized by

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a

200 mL of 0.2 N HCl

b

100 mL of 0.1 N HCl

c

100 mL of 0.2 N HCl

d

200 mL of 0.4 N HCl

answer is A.

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Detailed Solution

NH2CONH2 + 2NaOH 2NH3 + Na2CO3
From this, 1 mole urea gives 2 mole ammonia.
Therefore, moles of urea = 0.6/ 60 = 0.01 mole; moles of ammonia = 2x0.01 = 0.02 mole
Similarly, by balancing the other reaction, 0.02 mole NH3 requires 0.02 mole HCl.
We know, for 0.2 M HCl,
Molarity = Moles Volume 0.2 = Moles of HCl1001000 Moles of HCl = 0.02 mol HCl
Hence, correct option is: (A) 100mL of 0.2 N HCl 

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