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Q.

The  ammonia  prepared  by  treating  ammonium  sulphate  with  calcium  hydroxide  is completely used by NiCl2.6H2O to form a stable coordination compound. Assume that both the reactions are 100% complete.  If 1584 g of ammonium sulphate and 952 g of NiCl2.6H2O are used in the preparation, the combined weight  (in grams) of gypsum and the nickel-ammonia coordination compound thus produced is (Atomic weights in g mol-1: H = 1, N = 14, O = 16, S = 32, Cl = 35.5, Ca = 40, Ni = 59)

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answer is 2992.

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Detailed Solution

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(NH4)2 SO4+ Ca(OH)2  CaSO4.2H2O+2NH3

               1584 g                           gypsum ( M =172)    24mole

              =12 mol                          =   12 mol 

NiCl2.6H2O952g=4mol+6NH324molNiNH36M=2324molCl2+6H2O

Total mass =12×172+4×232=2992g

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