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Q.

The amount of arsenic pentasulphide that can be obtained when 35.5 g arsenic acid is treated with excess H2S in the presence of cone. HCl (assuming 100% conversion) is:

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a

 0.125 mol

b

 0.50 mol 

c

0.25 mol 

d

 0.333 mol

answer is D.

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Detailed Solution

 Molar mass of arsenic acid H3AsO4,is  M=(3+74.92+4×16)gmol1=143.42gmol1

Arsenic pentasulphide is As2 S5 .

2 mol of H3AsO4 will provide 1 mol of As2 S5 .

35.5g(=(35.5/143.92)mol)4 of H3AsO4will provide 1235.5143.92mol of As2O5

which is  0.123 mol

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The amount of arsenic pentasulphide that can be obtained when 35.5 g arsenic acid is treated with excess H2S in the presence of cone. HCl (assuming 100% conversion) is: