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Q.

The amount of sodium hydrogen carbonate, NaHCO3, in an antacid tablet is to be determined by dissolving the tablet in water and titrating the resulting solution with hydrochloric acid. Which indicator is the most appropriate for this titration?

AcidKa
H2CO32.5×104
HCO32.5×108

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a

alizarin yellow pKIn=12.5

b

methyl orange, pKIn=3.7

c

bromothymol blue, pKIn=7.0

d

phenolphthalein, pKIn=9.3

answer is A.

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Detailed Solution

Methyl orange is most suitable. Methyl orange is a frequently used pH indicator in titrations because of its straightforward and obvious colour shift. Due to the fact that it changes colour at the pH of a moderate acid, it is frequently employed in acid titrations. Methyl orange changes colour from yellow in a basic medium to red in an acidic one.

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