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Q.

The appropriate reagents required for carrying out the following transformation are

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a

 (i) succinic anhydride, FeCl3;( ii ) LiAlH 4; (iii) H2SO4

b

 (i) maleic anhydride, AlCl3 ; (ii)H2 N-NH2,KOH;(iii)H2SO4

c

 pthalic anhydride, F3 B.OEt 2;(ii)HSCH22SH,H+;(iii) Raney Ni;      (iv)polyphosphoric acid

d

 (i) succinic anhydride, AlCl3:(ii)Zn/Hg,HCl;(iii) polyphosphoric acid 

answer is A.

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Detailed Solution

(a) first step of the reaction is Friedel Craft acylation. This is followed by reduction in the next step, and intramolecular Friedel Craft acylation in the subsequent step.

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Reduction of ketone give carboxylic acid. We can go for another acylation which is intramoelcular in the presence of strong acid i.e. phosphoric acid.

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The appropriate reagents required for carrying out the following transformation are