Q.

The atomic radii of alkali metals (M) lie in the order Li<Na<K<Rb but the radii of M+ in aqueous solution lie in the reverse order Li+>Na+>K+>Rb+  What is the reason for this reverse order (on going from Li to Rb)

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a

Decreasing degree of hydration

b

Gradual increase in ionisation energy

c

increasing electropositive character

d

Increasing weakness of the metallic bond

answer is D.

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Detailed Solution

Small atomic size has more tendency of hydration, so as the size increases tendency for hydration also decreases.

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