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Q.

The atomic volume for a solid crystalline metal is (19.2 × 2 ) cm3/mol. The maximum atomic radius (in A°) for the metal atom is

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a

3

b

2

c

96

d

51

answer is B.

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Detailed Solution

d =ZMNA a3 g/cm3 1d = NA a3ZM cm2 / gm atomic volume 1d = NA a3Z cm2 / mol  a3  =atomic volume × ZNA Maximum occupancy occurs in FCC a= 22r  22r3 = 19.22×46.02×1023 162r3 = 19.22× 46.02 ×1023   r3 = 19.24×6.02×1023 r3 = 0.79 × 10-23 r3 = 7.9× 10-24 cm3 r =2× 10-8 cm r = 2 A°

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